Influence of Obtainment Conditions and Excitation Into Spectral and Kinetic Characteristics of Cathodoluminescence in Y2O3:Eu Thin Films
DOI:
https://doi.org/10.15330/pcss.18.1.84-88Keywords:
yttrium oxide, cathodoluminescence, thin filmsAbstract
The spectra and kinetics of the rise and decay of the cathodoluminescence (CL) of thin films of Y2O3:Eu obtained by RF-magnetron sputtering were investigated. Based on the shape of the CL spectra at different excitation energies, it showed the possibility of creating irregular solutions of yttrium and europium oxides and the structural features of the surface and bulk layers. The time constant for the decay CL for 612 nm emission was determined and the value of which is within the range (1.8 - 4.1) ms. This value is a complex function of the type of film deposition atmosphere, the activator concentration, and the duration of the exciting pulses was shown. The features of the risen CL and the proposal based on the delayed rise CL analyze structural perfection of Y2O3:Eu thin films.
References
H. J. Lee, K. P. Kim, G. Y. Hong, J. S. Yoo, J. Luminescence 130 (6) 941 (2010).
Q. Dai, M. E. Foley, C. J. Breshike, A. Lita, G. F. Strouse, J. Am. Chem. Soc. 133 (39) 15475 (2011).
G. Ju, Y. Hu, L. Chen, X. Wang, Z. Mu, H. Wu, F. Kang, J. Luminescence 132 (8) 1853 (2012).
C. Shanga, X. Shang, Y. Qu, M. Li, Chem. Phys. Lett. 501 480 – 484 (2011).
T. A. Pomelova, V. V. Bakovets, I. V. Korol’kov, O. V. Antonova, I. P. Dolgovesova, Phys. Solid State 56 (12) 2496 (2014).
N. Yamamoto, Cathodoluminescence (InTech, Croatia, 2012).
O. M. Bordun, I. O. Bordun, I. Yo. Kukharskyy, J. Appl. Spectrosc. 82 (3) 390 (2015).
N. C. Chang, J. B. Gruber, J. Chem. Phys. 41 (10) 3227–3234 (1964).
G. Blasse, B. C. Grabmaier, Luminescent Materials (Springer-Verlag, Berlin, 1994).
S. Som, S.K. Sharma, S.P. Lochab, Mater. Res. Bull. 48 (2) 844 (2013).
H. S. Yoo, W. B. Im, S. W. Kim, B. H. Kwon, D. Y. Jeon, J. Luminescence 130 (1) 153 (2010).
R. M. Krsmanović, Ž. Antić, M. G. Nikolić, M. Mitrić, M. D. Dramićanin, Ceram. Int. 37 (2) 525 (2011).
F. C. Romo, A. G. Murillo, D. L. Torres, N. C. Castro, V. H. Romero, E. Rosa, V. G. Febles, M. G. Hernández, Opt. Materials 32 (11) 1471 (2010).
W.-N. Wang, W. Widiyastuti, T. Ogi, I. W. Lenggoro, K. Okuyama, Chem. Mater. 19 (7) 1723 (2007).
G. S. Gowd, M. K. Patra, S. Songara, A. Shukla, M. Mathew, S. R. Vadera, N. Kumar, J. Luminescence 132 (8) 2023 (2012).
R. Srinivasan, N. R. Yogamalar, J. Elanchezhiyan, R. J. Joseyphus, A. C. Bose, J. Alloys Comp. 496 (1–2) 472 (2010).
D. T. Sviridov, Yu. F. Smirnov, Theory of optical spectra of ions of transition metals (Nauka, Moskva, 1977).
U. Herr, H. Kaps, A. Konrad, Solid State Phenom. 94 85 (2003).
R. Schmechel, M. Kennedy, H. von Seggern, H. Winkler, M. Kolbe, R. A. Fischer, L. Xaomao, A. Benker, M. Winterer, H. Hahn, J. Appl. Phys. 89 (3) 1679 – 1686 (2001).
H. Kaps, M. L. Arefin, U. Herr, H. Paul, Sol. State Phenom. 128 165 – 172 (2007).
P. K. Sharma, R. K. Dutta, A. C. Pandey, Adv. Mat. Lett. 2 (4) 285 – 289 (2011).
C. Hang, Z. Pei-Fen, Z. Hong-Yang, L. Hong-Dong, C. Qi-Liang, Chin. Phys. B 23 (5) 057801 (2014).