Fabrication and Tailored Structural and Dielectric characteristics of (SrTiO3/ NiO ) Nanostructure Doped (PEO/PVA) polymeric Blend for Electronics Fields
DOI:
https://doi.org/10.15330/pcss.23.4.785-792Keywords:
polymer blend, electrical properties, SrTiO3/NiO, nanoparticles, structural propertiesAbstract
Films are prepared from (PEO/PVA) blend with various ratios of (SrTiO3/NiO) by using casting method. SEM images of (PEO/PVA/SrTiO3/NiO) nanocomposites show that many aggregates or chunks on the upper surface that are homogeneous and coherent. The (PEO/PVA/SrTiO3/NiO) nanocomposites contribute to tiny vibrational molecular movement, according to the (FTIR) analysis. Several polymer chains were also disrupted once (SrTiO3/NiO) nanoparticles were introduced. Instead, several additional chains were produced. Dielectric constant and dielectric loss decreases with increasing of frequency, while conductivity increases, as well as dielectric constant increases from 4.73 to 5.99 and dielectric loss rise from 0.85 to1.80, while the conductivity increases from 4.7×10-11 S/cm to 1.10×10-10 S/cm when (SrTiO3/NiO) NPs reached 4wt.%. The results of structural and electrical properties show that the (PEO/PVA/SrTiO3/NiO) NCs may be used for various electronics fields.
References
C. C. Okpal, Nanocomposites–an overview, Int. J.Eng. Res. Dev., 8 (11), 17 (2013) ; http://doi.org/10.4236/jmp.2013.412A1001.
Z M Elimat, A M Zihlif and G Ragosta, Study of a.c electrical properties of aluminum-epoxy composites, J. Phys. D: Appl. Phys., 41, 7 (2008); https://doi.org/10.1088/0022-3727/41/16/165408.
H.N. Obaid, M.A. Habeeb, F.L. Rashid, and A. Hashim, Thermal energy storage by nanofluids, Journal of Engineering and Applied Sciences, 8 (5), 143 (2013); http://doi.org/10.36478/jeasci.2013.143.145.
M A. Srivastava, K. Kumar Jana, P. Maiti, D. Kumar, and O. Parkash, Investigations on Structural, Mechanical, and Dielectric Properties of PVDF/Ceramic Composites, Journal of Engineering, 2015, 9 (2015), https://doi.org/10.1155/2015/205490.
M.A. Habeeb, W.K. Kadhim, Study the optical properties of (PVA-PVAC-Ti) nanocomposites, Journal of Engineering and Applied Sciences, 9 (4), 109 (2014); http://dx.doi.org/10.36478/jeasci.2013.143.145.
S. Mahendia, A.K. Tomar and Shyam Kumar, Electrical conductivity and dielectric spectroscopic studies of (PVA-Ag) nanocomposite films, Journal of Alloys and Compounds, 508(2), 406 (2010); https://doi.org/10.1016/j.jallcom.2010.08.075.
W. Li, Y. Pang, J. Liu, G. Liu, Y. Wang, and Y. Xia, A PEO-based gel polymer electrolyte for lithium ion batteries, Rsc Adv., 7(38), 234 (2017); https://doi.org/10.1039/C7RA02603J
V. M. Mohan, P. B. Bhargav, V. Raja, A. K. Sharma,and V. V. R. Narasimha Rao, Optical and electrical properties of pure and doped PEO polymer electrolyte films, Soft Mater., 5(1), 33 (2007); https://doi.org/10.1080/15394450701405291.
M.A. Habeeb, Effect of rate of deposition on the optical parameters of GaAs films, European Journal of Scientific Research, 57 (3), 478 (2011).
K.S. Ngai, S. Ramesh, K. Ramesh, and J. C. Juan, A review of polymer electrolytes: fundamental, approaches and applications, Ionics (Kiel)., 22(8), 1259 (2016); https://doi.org/10.1007/s11581-016-1756-4Corpus
A. H. Hadi , M. A. Habeeb, Effect of CdS nanoparticles on the optical properties of (PVA-PVP) blends, Journal of Mechanical Engineering Research an Developments, 44 (3), 265 (2021); https//jmerd.net/03-2021-265-274/
K.M. Dooley, S.Y. Chen, J.R. Ross, Stable Nickel- Containing Catalysts for the Oxidative Chupling of Methane, Journal of Catalysis, 145, 402 (1994); https://doi.org/10.1006/jcat.1994.1050.
N. Hayder, M.A. Habeeb, and A. Hashim, Structural, optical and dielectric properties of (PS-In2O3/ZnCoFe2O4) nanocomposites, Egyptian Journal of Chemistry, 63, 577 (2020); http://dx.doi.org/10.21608/ejchem.2019.14646.1887.
D. Vaishnav1 and R. K. Goyal, Thermal and Dielectric Properties of High-Performance Polymer/ZnO Nanocomposites, IOP Conf. Series: Journal of Materials Science and Engineering, 64, 1 (2014); http://dx.doi.org/10.1088/1757-899X/64/1/012016.
Q.M. Jebur, A. Hashim, and M.A. Habeeb, Structural, A.C electrical and optical properties of (polyvinyl alcohol-polyethylene oxide-aluminum oxide) nanocomposites for piezoelectric devices, Egyptian Journal of Chemistry, 63, 719 (2020); https://dx.doi.org/10.21608/ejchem.2019.14847.1900
R.A. McKee; F.J. Walker & M.F. Chisholm, Crystalline Oxides on Silicon The First Five Monolayers, Phys. Rev Lett., 81(14), 3014 (1998), Bibcode:PhRvL..81.3014M.1998; https://doi.org/10.1103/PhysRevLett.81.14
M.A. Habeeb, A. Hashim, and N. Hayder, Fabrication of (PS-Cr2O3/ZnCoFe2O4) nanocomposites and studying their dielectric and fluorescence properties for IR sensors, Egyptian Journal of Chemistry, 63, 709 (2020); https://dx.doi.org/10.21608/ejchem.2019.13333.1832.
S. Islam, G. B. V. S. Lakshmi, A.M. Siddiqui, M. Husain, Synthesis, characterization and low frequency AC conductivity of polyaniline/niobium pentoxide composites, Synthetic Metals, 307525 (2013) ; https://doi.org/10.1155/2013/307525.
A. Hashim, M.A. Habeeb, and Q.M. Jebur, Structural, dielectric and optical properties for (Polyvinyl alcohol-polyethylene oxide manganese oxide) nanocomposites, Egyptian Journal of Chemistry, 63 ,735 (2020); https://dx.doi.org/10.21608/ejchem.2019.14849.1901.
Q.M. Jebur, A. Hashim, and M.A. Habeeb, Fabrication, structural and optical properties for (Polyvinyl alcohol-polyethylene oxide iron oxide) nanocomposites, Egyptian Jour of Chemistry, 63 (2), 611 (2020); https://dx.doi.org/10.21608/ejchem.2019.10197.1669
K. Praveenkumar, T. Sankarappa, J. S. Ashwajeet and R. Ramanna, Dielectric and AC conductivity studies in PPy-Ag nanocomposites, J. Polym., (2015); http://dx.doi.org/10.1155/2015/893148.
M. A. Habeeb, W.S. Mahdi, Characterization of (CMC-PVP-Fe2O3) nanocomposites for gamma shielding application, International Journal of Emerging Trends in Engineering Research, 7 (9), 247 ( 2019), http://dx.doi.org/10.30534/ijeter/2019/06792019.
J. Selvi, S. Mahalakshmi and V. Parthasarathy, Synthesis, structural, optical, electrical and thermal studies of polyvinyl alcohol/CdO nanocomposite films, Journal of Inorganic and Organometallic Polymers and Materials, 27, 1918 (2017), http://dx.doi.org/10.1007/s10904-017-0662-1.
M.A. Habeeb, R.S.A. Hamza, Synthesis of (polymer blend –MgO) nanocomposites and studying electrical properties for piezoelectric application", Indonesian Journal of Electrical Engineering and Informatics, 6 (4), 428 (2018); http://dx.doi.org/10.11591/ijeei.v6i1.511.
N.K. Abbas, M.A. Habeeb, and A.J.K. Algidsawi, Preparation of chloro penta amine cobalit (III) chloride and study of its influence on the structural and some optical properties of polyvinyl acetate, International Journal of polymer Science, 926789(2015); https://doi.org/10.1155/2015 /926789.
W.Yingkang, Y.Yang, and , R. Ruicheng , A Study on Poly (Ethylene Oxide)/Poly (Vinyl Acetate) Blends, Polymer communications, (3), 289 (1985); https://doi.org/10.1002/pol.1982.180200712
M.A. Habeeb, R.S. Abdul Hamza, Novel of (biopolymer blend-MgO) nanocomposites: Fabrication and characterization for humidity sensors, Journal of Bionanoscience, 12 (3), 328 (2018); https://doi.org/10.1166/jbns.2018.1535
S. Hegde, V. Ravindrachary, S.D. Praveena, B. Guruswamy, R.N. Sagar, Optical and dielectric properties of Li + ion conducting solid polymer electrolyte, Indian J. Adv. Chem. Sci., (2018); http://dx.doi.org/10.22607/IJACS.2018.602004.
M.A. Habeeb, A. Hashim, N. Hayder, Structural and optical properties of novel (PS-Cr2O3/ZnCoFe2O4) nanocomposites for UV and microwave shielding , Egyptian Journal of Chemistry, 63, 697 (2020); https://dx.doi.org/10.21608/ejchem.2019.12439.1774.
H.N. Chandrakala, B. Ramaraj, Shivakumaraiah, G.M. Madhu, Siddaramaiah, Investigation on the influence of sodium zirconate nanoparticles on the structural characteristics and electrical properties of polyvinyl alcohol nanocomposite films, Journal of Alloys and Compounds, 551, 531 (2013); http://dx.doi.org/10.1016/j.jallcom.2012.10.188.
S. Atiq ,S.Ishaq, M.Moussa ,Dielectric and impedance spectroscopic studies of three phase graphene/titania/poly(vinyl alcohol) nanocomposite films, Results in Physics 11, (2018) http://dx.doi.org/10.1016/j.rinp.2018.09.049.
S. M. Mahdi , M. A. Habeeb , Evaluation of the influence of SrTiO3 and CoO nanofillers on the structural and electrical polymer blend characteristics for electronic devices, Digest Journal of Nanomaterials and Biostructures, 17 (3), 941 (2022); https://doi.org/10.15251/DJNB.2022.173.941
B. M Mustafa, A. Y. Konul, M. E. Goncha, K. M. Rasim and Z. S. Aytan, Study of Dielectric Properties of CdS/PVA Nanocomposites Obtained by Using Successive Ionic Layer Adsorption and Reaction, World Journal of Condensed Matter Physics, 3, 82 (2013); http://dx.doi.org/10.4236/wjcmp.2013.31014.
S. M. Mahdi , M. A. Habeeb , Synthesis and augmented optical characteristics of PEO–PVA–SrTiO3–NiO hybrid nanocomposites for optoelectronics and antibacterial applications, Optical and Quantum Electronics, 54 (12) : 854 (2022); https://doi.org/10.1007/s11082-022-04267-6
J. Thomasukutty, C. G. Soney, M. Maya and T. Sabu, Functionalized MWCNT and PVA Nanocomposite Membranes for Dielectric and Pervaporation Applications, J. Chemical Engineering and Process technology, 6 (3), 1 (2015); http://dx.doi.org/10.4172/2157-7048.1000233.
A. H. Hadi, M. A. Habeeb, The dielectric properties of (PVA-PVP-CdS) nanocomposites for gamma shielding applications, Journal of Physics: Conference Series,1973(1),012063 (2021); http://dx.doi.org/10.1088/1742-6596/1973/1/012063.
V.S Sangawar, R.J. Dhokne, A.U. Ubale, P.S. Chikhalikar, S.D. Meshram, Structural characterization and thermally stimulated discharge conductivity (TSDC) study in polymer thin films, Bull. Mater. Sci., 30(2), 163 )2007); http://dx.doi.org/10.1007/s12034-007-0029-2.
M.A. Habeeb, Dielectric and optical properties of (PVAc-PEG-Ber) biocomposites, Journal of Engineering and Applied Sciences, 9 (4), 102 (2014); http://doi.org/10.36478/jeasci.2014.102.108.
A.Choudhury, Dielectric and piezoelectric properties of ppolyetherimide/BaTiO3 nanocompsites, Mater. Chem. Phys., 121, 280 (2010), http://doi.org/10.1016/j.matchemphys.2010.01.035.
E. Sheha, N. Mona and M K El-Mansy, Characterization of poly (vinyl alcohol)/poly(3,4-ethylenedioxythiophene) poly (styrenesulfonate) polymer blend: structure, optical absorption, electrical and dielectric properties, Physica Scripta, 88 (3), (2013); http://dx.doi.org/10.1088/0031-8949/88/03/035701.
A. Chandrakala, B. Ramaraj, j. Shivakumaraiah, G.M. Madhu, S. Siddaramaiah, The influence of zinc oxide–cerium oxide nanoparticles on the structural characteristics and electrical properties of polyvinyl alcohol films, J Mater Sci., 47, 8076 (2012); http://dx.doi.org/10.1007/s10853-012-6701-y.
Downloads
Published
How to Cite
Issue
Section
