Sulfidation of Zinc oxide by interaction with Antimony sulfide

V.F. Zinchenko; I.R. Magunov; G.V. Volchak; O.S. Mazur; O.H. Ieriomin; S.V. Kuleshov; P.G. Doha; A.V. Babenko

doi:10.15330/pcss.25.2.399-405

Authors

V.F. Zinchenko O.V. Bogatsky Physico-Chemical Institute NAS of Ukraine, Odesa, Ukraine
I.R. Magunov O.V. Bogatsky Physico-Chemical Institute NAS of Ukraine, Odesa, Ukraine
G.V. Volchak O.V. Bogatsky Physico-Chemical Institute NAS of Ukraine, Odesa, Ukraine
O.S. Mazur O.V. Bogatsky Physico-Chemical Institute NAS of Ukraine, Odesa, Ukraine
O.H. Ieriomin O.V. Bogatsky Physico-Chemical Institute NAS of Ukraine, Odesa, Ukraine
S.V. Kuleshov V.I. Vernadsky Institute of General and Inorganic Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine
P.G. Doha O.V. Bogatsky Physico-Chemical Institute NAS of Ukraine, Odesa, Ukraine
A.V. Babenko O.V. Bogatsky Physico-Chemical Institute NAS of Ukraine, Odesa, Ukraine; Odesa I.I. Mechnikov National University, Odesa, Ukraine

DOI:

https://doi.org/10.15330/pcss.25.2.399-405

Keywords:

Zinc oxide, Antimony sulfide, acid-base interaction, sulfidation

Abstract

The mechanism of interaction between ZnO and Sb₂S₃ in the temperature range of 500-700°С was studied. The methods of differential thermal analysis, X-ray diffraction, diffuse reflectance spectroscopy and IR transmission spectroscopy, as well as thermodynamic calculations established the exchangeable acid-base reaction mechanism with the removal of the most volatile of the products – Sb₂O₃. The final and only product of interaction in the system is ZnS of cubic modification (sphalerite) without phase impurities. Condensate mainly contains Antimony oxides of various compositions. In the same way, it is possible to remove oxygen-containing impurities (mainly ZnO) from zinc sulfide obtained by the method of self-propagating high-temperature synthesis.

Author Biography

P.G. Doha, O.V. Bogatsky Physico-Chemical Institute NAS of Ukraine, Odesa, Ukraine

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