Thermodynamic investigations of the erbium tellurides by EMF method

S. Z. Imamaliyeva; I. F. Mehdiyeva; D. B. Taghiyev; M. B. Babanly

doi:10.15330/pcss.21.2.312-318

Authors

S. Z. Imamaliyeva Institute of Catalysis and Inorganic Chemictry
I. F. Mehdiyeva Institute of Catalysis and Inorganic Chemistry named after acad.M.Nagiyev, Azerbaijan National Academy of Sciences
D. B. Taghiyev Institute of Catalysis and Inorganic Chemistry named after acad.M.Nagiyev, Azerbaijan National Academy of Sciences
M. B. Babanly Institute of Catalysis and Inorganic Chemistry named after acad.M.Nagiyev, Azerbaijan National Academy of Sciences

DOI:

https://doi.org/10.15330/pcss.21.2.312-318

Keywords:

phase diagram, erbium tellurides, EMF method, thermodynamic functions

Abstract

The work presents the results of a thermodynamic study of the Er-Te system by the method of electromotive forces (EMF) in the temperature range of 300-450 K. From the EMF measurements of the concentration cells relative to the Er and ErTe electrodes, the partial thermodynamic functions of ErTe and Er in the alloys are determined, based on which the standard thermodynamic formation functions and the standard entropies of the intermediate compounds ErTe₃, Er₂Te₃, and ErTe are calculated. A comparative analysis of the obtained data with the literature is carried out.

References

A.R. Jha. Rare Earth Materials: Properties and Applications (CRC Press, United States, 2014).

Y. Sc, La-Lu, Gmelin Handbock of lnorganic Chemistry, in: Hartmut Bergmann (Ed.), Rare Earth Elements, 8th Edition (Springer-Verlag Heidelberg GmbH, Berlin, 1987).

T.Vo, P. von Allmen, C.-H. Huang, J.M.Ma, S.K. Bux, J.-P. Fleurial, Appl. Phys. 116, 133701 (2014) (https://doi.org/10.1063/1.4896670).

D. Cheikh, B.E. Hogan, T. Vo, P von Allmen, K. Lee, D.M. Smiadak, A. Zevalkink, B.S. Dunn, J.-P. Fleurial, S.K. Bux, Joule 2, 698 (2018) (https://doi.org/10.1016/j.joule.2018.01.013).

A.F. May, J.-P. Fleurial, G.J. Snyder, Phys. Rev. B 78, 125205 (2008) (https://doi.org/10.1103/PhysRevB.78.125205).

I.P. Muthuselvam, R. Nehru, K.R. Babu, K. Saranya, S.N. Kaul, S-M. Chen, W-T. Chen, Y. Liu, G-Y Guo, F. Xiu, R. Sankar, J. Physics: Condensed Matter. 31(28), 285802 (2019) (https://doi.org/10.1088/1361-648X/ab1570).

M. Saint-Paul, P. Monceau, Advances in Condensed Matter Physics (4), 1 (2019) (https://doi.org/10.1155/2019/2138264).

M.D. Regulacio, K. Bussmann, B. Lewis, S.L. Stoll, Journal of the American Chemical Society 128(34), 11173 (2006) (https://doi.org/10.1021/ja0620080).

Q.H. Li, X. Jin, Y. Yang, H.N. Wang, H.J. Xu, Y.Y. Cheng, T.H. Wei, Y.C. Qin, X.B. Luo, W.F. Sun, S.L. Luo, Adv. Funct. Mater 26(2), 254 (2016) (https://doi.org/10.1002/adfm.201503433).

P. Wachter. Critical reviewers in solid state and materials sciences 3(2), 189 (1972) (https://doi.org/10.1080/10408437208244865).

A.S. Verma, African Phys.Rev. 3, 11 (2009).

M.A. Kuroda, Z. Jiang, M. Povolotskyi, G. Klimeck, D.M. Newns, G.J. Martyna, Physical Review B 90, 245124 (2014) (https://doi.org/10.1103/PhysRevB.90.245124).

A.T. Filip, P. LeClair, C.J.P. Smits, J.T. Kohlhepp, H.J.M. Swagten, B. Koopmans, and W.J.M. de Jonge, Appl. Phys. Lett 81, 1815 (2002) (https://doi.org/10.1063/1.1503406).

O.V. Andreev, V.G. Bamburov, L.N. Monina, Razumkova, A.V. Ruseykina, O.Yu. Mitroshin, V.O. Andreev. Fazovie ravnovesiya v sistemax sulfidov 3d-, 4f-elementov. (RIO URO RAN, Ekatirinburq, 2015. (In Russian).

M.B. Babanly, E.V. Chulkov, Z. S. Aliev, A.V. Shevel’kov, I. R. Amiraslanov, Russ. J. Inorg. Chem. 62(13), 1703 (2017) (https://doi.org/10.1134/S0036023617130034).

S.Z.Imamaliyeva, D.M. Babanly, D.B. Tagiev, and M.B. Babanly. Russ. J. Inorg. Chem, 63(13), 1703 (2018) (https://doi.org/10.1134/S0036023618130041).

M.B. Babanly, L.F. Mashadiyeva, D.M. Babanly, S.Z. Imamaliyeva, D.B. Taghiyev, Y.A. Yusibov, Russian J. Inorg.Chem. 64(13), 1649 (2019) (https://doi.org/10.1134/S0036023619130035).

T.B. Massalski. Binary alloys phase diagrams, second edition. (ASM International, Materials park, Ohio, 1990).

Diagrammi sostoyaniya dvoynikh metallicheskikh system. Ed. Lyakishev N.P. (Mashinostroenie, Moscow, v.2, 1997).

O. Кubaschewski, C.B. Alcock. P.J. Spencer, Materials Thermochemistry. (Oxford; New York : Pergamon Press, 1993).

V.S. Yunqman, Baza dannix termicheskix constant veshestv. Elektronnaya versiya pod. red. 2006 q., http://www.chem.msu.su/cgi-bin/tkv (In Russian).

K.A. Sharifov, Z.Sh. Karaev, T.Kh. Azizov, Izv Akad. Nauk SSSR, Neorg. Mater. 3(4), 719 (1967).

V.P. Vasiliev, V.I. Goryacheva, Y.I. Gerasimov, T.S. Lazareva, Bulletin of Moscow. University. Ser. Chim. 21(4), 339 (1980).

K.C. Mills, Thermodynamic Data for lnorganic Sulphides, Selenides, and Tellurides (Butter-worth, London 1974).

V.P. Vassiliev, V.A. Lysenko, Electrochimica Acta 222, 1770 (2016) (https://doi.org/10.1016/j.electacta.2016.11.075).

V.P. Vassiliev, V.A. Lysenko, M. Gaune-Escard, Pure Appl.Chem. 91(6), 879 (2019) (https://doi.org/10.1515/pac-2018-0717).

I.F. Mekhdiyeva, Fizika, 3, 25 (2019).

S.Z. Imamalieva, D.M. Babanly, T.M. Gasanly, D.B. Tagiev, and M.B. Babanly, Russian Journal of Physical Chemistry A, 92(11), 2111 (2018) (https://doi.org/10.1134/S0036024418110158).

D.M. Babanly, L.F. Mashadieva, M.B. Babanly, Inorg. Mater. 53(5), 519 (2017)(https://doi.org/10.1134/S002016851705003X).

D.M. Babanly, G.M. Velieva, S.Z. Imamaliyeva, M.B. Babanly, Russ. J. Phys. Chem. A 91(7), 1170 (2017) (https://doi.org/10.1134/S0036024417070044).

S.Z. Imamaliyeva, T.M. Gasanly, M.A. Mahmudova, F.M. Sadygov, Physics, XXII(4), 19 (2017).

Y.I. Jafarov, S.A. Ismaylova, Z.S. Aliev, S.Z. Imamaliyeva, Y.A. Yusibov, M.B. Babanly, CALPHAD 55, 231 (2016) (https://doi.org/10.1016/j.calphad.2016.09.007).

D. M. Babanly, I.M. Babanly, S.Z. Imamaliyeva, V.A. Gasimov, A.V. Shevelkov, J.Alloys. Compd 590, 68 (2014) (https://doi.org/10.1016/j.jallcom.2013.11.223).

V. Vassiliev, W. Gong, Electrochemical Cells with the Liquid Electrolyte in the Study of Semiconductor, Metallic and Oxide Systems. In. Electrochemical Cells – New Advances in Fundamental Researches and Applications. Ed.Yan Shao, (IntechOpen, 2012).

A.G. Morachevskij, G.F. Voronin, V.A. Gejderikh, I.B. Kuczenok, Elektrokhimicheskie metody issledovaniya v termodinamike metallicheskikh sistem (ICzK. Akademkniga, 2003).

M.B. Babanly, Yu.A. Yusibov, Elektrokhimicheskie metody v termodinamike neorganicheskikh sistem (ELM, Baku, 2011).

M.B. Babanly, Y.A. Yusibov, N.B. Babanly, The EMF method with solid-state electrolyte in the thermodynamic investigation of ternary Copper and Silver Chalcogenides. In. Electromotive force and measurement in several systems. Ed.S.Kara. (Intechweb.Org, 2011).

A.N. Kornilov, L.B. Styopina, V.A. Sokolov, Russian J. Phys.Chem. 46(11), 2974 (1972).

I. Barin, Thermochemical Data of Pure Substances, Third Edition, (VCH, 2008).

A.T. Dinsdale, Calphad 15(4), 317 (1991) (https://doi.org/10.1016/0364-5916(91)90030-N).