Electrical properties of composites based on nanoporous carbon material
DOI:
https://doi.org/10.15330/pcss.21.3.409-414Keywords:
Mott-Schottky model, nanoporous carbon material, flat-band potentialAbstract
In this work, the morphological and electrical properties of the composite nanoporous carbon material/thermally expanded graphite or acetylene black have been investigated. Nanoporous carbon material was obtained from plant materials by its thermochemical activation based on potassium hydroxide. The dependence of the specific capacity of the nanoporous carbon/electrolyte electrochemical system on the applied potential was determined by the impedance spectroscopy method. Furthermore, the concentration of charge transfer and the density of states, as well as the flat-band potential of the system under research, were determined based on the Mott-Schottky model.
References
Lan Xia, L. Yu, D. Hua, G.Z. Chen, Mater. Chem. Front. 1(4), 584 (2017) (http://doi.org/10.1039/C6QM00169F).
B.K. Ostafiychuk, I.M. Budzulyak, B.I. Rachiy, R.P. Lisovsky, V.I. Mandzyuk, P.I. Kolkovsky, R.I. Merena, M.V. Berkeshchuk, L.V. Golovko, J. Nano- Electron. Phys. 9(5), 05001 (2017) (http://doi.org/10.21272/jnep.9(5).05001).
B.I. Rachiy, I.M. Budzulyak, V.M. Vashchynsky, N.Y. Ivanichok, M.O. Nykoliuk, Nanoscale Res. Lett. 11(1), 1 (2016) (http://doi.org/10.1186/s11671-016-1241-z).
P. Kurzweil AC, Impedance Spectroscopy – a powerful tool for the characterization of materials and electrochemical power sources, Proc. 12-th Int. Seminar on Double Layer Capacitors and Similar Energy Storage Devices (Deerfield Beach, Florida, USA, 2004). P. 18 (https://www.oth-aw.de/files/oth-aw/Professoren/Kurzweil/PK_Florida2004.pdf).
A.I. Kachmar, V.M. Boichuk, I.M. Budzulyak, V.O. Kotsyubynsky, B.I. Rachiy, R.P. Lisovskiy, Fuller Nanotub Car N. 27(9), 669 (2019) (http://doi.org/10.1080/1536383X.2019.1618840).
G. Natu, P. Hasin, Z. Huang, Z. Ji, M. He, Y. Wu, ACS Appl Mater Interfaces. 4(11), 5922 (2012) (http://doi.org/10.1021/am301565j).
F. La Mantia, H. Habazaki, M. Santama¬ria, F. Di Quarto, Russ. J. Electrochem. 46, 1306 (2010) (http://doi.org/10.1134/S102319351011011X).
B.K. Ostafiychuk, I.M. Budzulyak, B.I. Rachiy, V.M. Vashchynsky, V.I. Mandzyuk, R.P. Lisovsky, L.O. Shyyko, Nanoscale Res Lett. 10(1), 1 (2015) (http://doi.org/10.1186/s11671-015-0762-1).
A.P. Karnaukhov, Adsorption. The texture of dispersed and porous materials (Novosibirsk, Science, Sib. enterprise RAN Publ., 1999) (https://www.twirpx.com/file/1369122/).
M. Hahn, M. Baertschi, O. Barbieri, J.C. Sauter, R. Kötz, and R. Gallay, Electrochem. and solid –st. Letters 7(2), 33 (2004) (https://iopscience.iop.org/article/10.1149/1.1635671/meta).
K.A. Kazdobin, E.D. Pershina, Impedance Spectroscopy of the Electrolytic Materials, Ukraine, 224 (2012) (https://www.researchgate.net/publication/274634354_Impedance_manualUA),
A.N. Frumkin, Potentsialy nulevogo zaryada (The Potentials of Zero Charge) (Nauka, Moscow, 1979) (https://www.twirpx.com/file/1621717/).
B.B. Damaskin, O.A. Petrii, G.A. Tsirlina, Electrochemistry, the 2nd Edition (Koloss-Khimiya, Moscow, 2006) (http://www.chem.msu.ru/rus/books/2015/damaskin/welcome.html).
B.P. Bahmatyuk, A.S. Kurepa, I.I. Grygorchak, Visnyk of Lviv Polytechnic National University, Series of Physical and mathematical sciences 687, 188 (2010) (http://vlp.com.ua/node/5960).
Y. Zhou, T. Holme, J. Berry, T.R. Ohno, D. Ginley, R. O’Hayre, J. Phys. Chem. C. 114, 506 (2010) (http://doi.org/10.1021/jp9088386).
H. Mc Gerischer, R. Intyre, D. Scherson, W. Storck, J. Phys. Chem. 91, 1930 (1987) (http://doi.org/10.1021/j100291a049).
R. Memming, Semiconductor Electro¬chemistry (Wiley-VCH Verlag GmbH, Weinheim, Germany, 2001) (https://www.wiley.com/en-us/Semiconductor+Electrochemistry%2C+2nd+Edition-p-9783527312818).
M. Itagaki, S. Suzuki, I. Shitanda, K. Watanabe, H. Nakazawa, J. Power Sources. 161, 415 (2007) (http://doi.org/10.1016/j.jpowsour.2006.09.077).
B.E. Conway, Electrochemical superca¬pacitors – scientific fundamentals and techno¬logical applications (The Kluwer Academic Plenum, NY, 1999) (https://www.springer.com/gp/book/9780306457364).