Tl4GdTe3 and Tl4DyTe3 – novel structural Tl5Te3 analogues

S. Imamaliyeva

doi:10.15330/pcss.21.3.492-495

Authors

S. Imamaliyeva Institute of Catalysis and Inorganic Chemictry

DOI:

https://doi.org/10.15330/pcss.21.3.492-495

Keywords:

thallium-REE tellurides, differential-thermal analysis, powder X-ray diffraction, crystal lattice

Abstract

The novel ternary compounds Tl₄GdTe₃and Tl₄DyTe₃- structural analogs of Tl₅Te₃ (Sp.gr.I4/mcm), were synthesized and identified by DTA and XRD methods. From powder XRD data, their crystal lattices parameters were calculated: a=8.8766(7), c=13.0846 (13) Å, Z=4 (Tl₄GdTe₃); a=8.8588 (9), c=13.0524(16) Å, Z=4 (Tl₄DyTe₃). It was found that the synthesized compounds melt with decomposition by peritectic reactions at 770 and 762 K, respectively.

References

Yu.P. Afinogenov, E.G. Goncharov, G.V. Semenova, V.P. Zlomanov, Physicochemical analysis of multicomponent systems (MPTI, Moscow, 2006).

M.B. Babanly, E.V. Chulkov, Z.S. Aliev, A.V. Shevelkov, and I.R. Amiraslanov, Russ. J. Inorg. Chem. 62(13), 1703 (2017) (https://doi.org/10.1134/S0036023617130034).

S.Z. Imamaliyeva, D.M. Babanly, D.B. Tagiev, and M.B. Babanly, Russ. J. Inorg. Chem. 63(13), 1703 (2018) (https://doi.org/10.1134/S0036023618130041).

M.M. Asadov, M.B. Babanly, A.A. Kuliev, Inorg. Mater. 13(8), 1407 (1977).

H. Okamoto, Te-Tl (Tellurium-Thallium). J. Phase Equilibria 21(5), 501(2001) (https://doi.org/10.1361/105497100770339833).

I. Schewe, P. Böttcher, H.G. Schnering, Z. Kristallogr. Bd188, 287 (1989) (https://doi.org/10.1524/zkri.1989.188.3-4.287).

P. Böttcher, Th. Doert, Ch. Druska, S. Brandmöller, J.Alloys Compd. 246, 209 (1997) (https://doi.org/10.1016/S0925-8388(96)02455-3).

M.B. Babanly, A. Akhmadyar, A.A. Kuliev, Russ. J. Inorg. Chem. 30, 1051 (1985).

M.B. Babanly, A. Akhmadyar, A.A. Kuliev, Russ. J. Inorg. Chem. 30(9), 2356 (1985).

A.A. Gotuk, M.B. Babanly, A.A. Kuliev, Inorg. Mater. 15, 1062 (1979).

S.Z. Imamaliyeva., F.M. Sadygov, M.B. Babanly, Inorg. Mater. 44, 935 (2008) (https://doi.org/10.1134/S0020168508090070).

M.B. Babanly, S.Z. Imamaliyeva, D.M. Babanly and F.M. Sadygov, Azerb. Chem. J. 1, 122 (2009).

M.B. Babanly, S.Z. Imamaliyeva, and F.M. Sadygov, Baku Univ.News. Ser. of nature study 4, 5 (2009).

K. Wacker, Z. Kristallogr. Supple. 3, 281 (1991).

T. Doert, P. Böttcher, Z. Kristallogr. 209, 95 (1994) (https://doi.org/10.1524/zkri.1994.209.1.95).

S. Bradtmöller, P. Böttcher, Z. anorg. allg. chem. 619, 1155 (1993) (https://doi.org/10.1002/zaac.19936190702).

M.B. Babanly, S.Z. Imamaliyeva, and F.M. Sadygov, Chem.Problems 1, 171 (2009).

A.Isaeva, R. Schoenemann, T. Doert, Crystals 10(4), 277 (2020) (https://doi.org/10.3390/cryst10040277).

M. Piasecki, M.G. Brik, I.E. Barchiy, K. Ozga, I.V. Kityk, A.M. El-Naggarf, A.A. Albassam, T.A. Malakhovskaya, G. Lakshminarayana, J. Alloys Compd. 710, 600 (2017) (https://doi.org/10.1016/j.jallcom.2017.03.280).

F. Heinke, L. Eisenburger, R. Schlegel, S. Schwarzmüller, O. Oeckle, Z. Anorg. Allg. Chem. 643, 447 (2017) (https://doi.org/10.1002/zaac.201600449).

Q. Guo, A. Assoud. H. Kleinke, Advanced Energy Materials, (14), 1400348 (2014) (https://doi.org/10.1002/aenm.201400348).

I.E. Barchij, M. Sabov, A.M. El-Naggar, N.S. AlZayed, A.A. Albassam, A.O. Fedorchuk, I.V. Kityk, J. Mater Sci: Mater Electron. 27, 3901 (2016) (https://doi.org/10.1007/s10854-015-4240-4).

K.E. Arpino, B.D. Wasser, T.M. McQueen, APL Mattr. 3(4), 041507 (2015) (https://doi.org/10.1063/1.4913392).

Q. Guo, H. Kleinke, J. Alloys Compd. 630, 37 (2015) (https://doi.org/10.1016/j.jallcom.2015.01.025).

K.J. Plucinski, M. Sabov, A.O. Fedorchuk, I.E. Barchij, L. Lakshminarayana, M. Filep, Opt.Quant. Electron. 47, 185 (2015) ( https://doi.org/10.1007/s11082-014-9899-x).

S. Bangarigadu-Sanasy, C.R. Sankar, P.A. Dube, J.E. Greedan, H. Kleinke, J. Alloy. Compd. 589, 389 (2014) (https://doi.org/10.1016/j.jallcom.2013.11.229).

S.Z. Imamaliyeva, V.A.Gasymov, M.B. Babanly, The Chemist 1, 1 (2017).

I.F. Mekhdiyeva, P.H. Babayeva, V.P. Zlomanov, S.Z. Imamaliyeva, New Materials, Compounds and Applications 3, 142 (2019).

S.Z. Imamaliyeva., G.I. Alakbarova, K.N. Babanly, I.R. Amiraslanov, M.B. Babanly, New Materials, Compounds and Applications 2(3), 221 (2018).