Thermodynamıc Propertıes of the BiTe and Bi8Te9 Compounds

G.S. Hasanova; A.I. Aghazade; Y.A. Yusibov; M.B. Babanly

doi:10.15330/pcss.21.4.714-719

Authors

G.S. Hasanova Ganja State University
A.I. Aghazade Institute of Catalysis and Inorganic Chemistry, Azerbaijan National Academy of Sciences
Y.A. Yusibov Ganja State University
M.B. Babanly Institute of Catalysis and Inorganic Chemistry, ANAS

DOI:

https://doi.org/10.15330/pcss.21.4.714-719

Keywords:

bismuth tellurides, thermodynamic functions, EMF method, ionic liquid

Abstract

Two-phase alloys Bi₈Te₉+Bi₄Te₅ and BiTe+Bi₈Te₉were studied by the electromotive forces method (EMF) in the temperature range 300-450 K. From the EMF data, the relative partial molar functions of bismuth in the alloys were calculated. The potential-forming reactions responsible for these partial functions were compiled, the values of the standard thermodynamic functions of formation, and the standard entropies of Bi₈Te₉ and BiTe compounds were calculated. A comparative analysis of the data for BiTe with the literature data was carried out; for Bi₈Te₉, the thermodynamic functions were obtained for the first time.

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