FT-IR Spectroscopic Study of the Radiation-Chemical Decomposition of n-Hexane on Nano-ZrO2

T.N. Agayev; N.N. Gadzhieva; S.Z. Melikova; Sh.Z. Musayeva; A.G. Aliyev

doi:10.15330/pcss.24.3.429-432

Authors

T.N. Agayev İnstitute of Radiation Problems, Ministry of Science and Education of Azerbaijan, Baku city, Azerbaijan
N.N. Gadzhieva İnstitute of Radiation Problems, Ministry of Science and Education of Azerbaijan, Baku city, Azerbaijan
S.Z. Melikova İnstitute of Radiation Problems, Ministry of Science and Education of Azerbaijan, Baku city, Azerbaijan
Sh.Z. Musayeva İnstitute of Radiation Problems, Ministry of Science and Education of Azerbaijan, Baku city, Azerbaijan
A.G. Aliyev İnstitute of Radiation Problems, Ministry of Science and Education of Azerbaijan, Baku city, Azerbaijan

DOI:

https://doi.org/10.15330/pcss.24.3.429-432

Keywords:

FT-IR spectroscopy, radiation-chemical decomposition, n-hexane, nano-ZrO2

Abstract

The radiation-chemical decomposition of n-hexane in the nano-ZrO₂ +n-hexane system under the action of gamma radiation at room temperature is studied by the method of Fourier-IR spectroscopy. The molecular and dissociative form of adsorption of n-hexane in zirconium nanodioxide was revealed. The intermediate products of the radiation-heterogeneous decomposition of n-hexane were analyzed.

References

N.N. Gadzhieva, Infrared spectroscopy of radiation stimulated processes of adsorption. radiolysis and hydrogenatation on the surface of metals in contact with hydrocarbons. In book: Infrared Spectroscopy principles. advances. and Applications. (IntechOpen, London, 125 (2018); DOI: 10.5772/intechopen.80431.

A. Cecal. D. Colisnic. K.P opa et all., Hydrogen yield from water radiolysis in the presence of zeolites. Central European Journal of chemistry. 29(1), 247 (2004); https://doi.org/10.2478/BF02476194.

Y. Maeda. Y. Kawana. Y. Kawanura. S. Hayami et all., Hydrogen Gas Evolution from Water Included in a Silica Gel Cavity and on Metal Oxides with γ-Ray Irradiation, Journal of Nuclear and Radiochemical Sciences, 6(2), 131 (2005); https://doi.org/10.14494/jnrs2000.6.2_131.

S. Seino. R. Fujimoto. T.A.Yamamoto, Hydrogen gas evolution from water dispersing nanoparticles irradiated with gamma-ray, Materials Research Society Symp. Proc. 608, 505 (1999); https://doi.org/10.1557/PROC-608-505.

S. Seino. T.A. Yamamoto. R. Fujimoto, Enhacement of hydrogen evolution yield from water dispersing nanoparticles irradiated with gamma-ray, Journal of Nuclear Science and Technology, 23(5), 633 (2001); https://doi.org/10.1080/18811248.2001.9715076.

T.N. Agayev. N.N. Gadzhieva. S.Z. Melikova, Fourier-Transform IR spectroscopic study of nano-ZrO2 + nano-SiO2+H2O systems upon the action of gamma radiation, Journal of Applied Spectroscopy, 85(2), 365 (2018); https://doi.org/10.1007/s10812-018-0658-9.