Magnetite nanoparticles synthesized using grape fruit extract:  synthesis, morphology, hyperthermia application and catalytic activity in hydrogen peroxide decomposition

Nazarii Danyliuk; Sofia Lischynska; Tetiana Tatarchuk; Volodymyr Kotsyubynsky; Volodymyr Mandzyuk

doi:10.15330/pcss.23.1.77-88

Authors

Nazarii Danyliuk Vasyl Stefanyk Precarpathian National University
Sofia Lischynska Vasyl Stefanyk Precarpathian National University
Tetiana Tatarchuk Vasyl Stefanyk Precarpathian National University
Volodymyr Kotsyubynsky Vasyl Stefanyk Precarpathian National University
Volodymyr Mandzyuk Vasyl Stefanyk Precarpathian National University

DOI:

https://doi.org/10.15330/pcss.23.1.77-88

Keywords:

green synthesis, magnetite, magnetic hyperthermia, catalytic activity, hydrogen peroxide

Abstract

The paper presents a simple one-step "green" approach to the synthesis of magnetite nanoparticles. The magnetite nanoparticles were synthesized using fruit extract obtained from grape peels and grape pulp. The formation of magnetite nanoparticles was confirmed by X-ray diffraction analysis (XRD), infrared spectroscopy (IR), Mössbauer spectroscopy, scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The crystallites sizes of magnetite nanoparticles are 7 and 14 nm for Fe₃O₄-peel and Fe₃O₄-pulp samples, respectively. Scanning electron microscopy images show that the samples consist of agglomerated nanoparticles. The synthesized magnetite nanoparticles showed good prospects for their use in magnetic hyperthermia. SAR values of 0.488 W/g and 1.330 W/g for Fe₃O₄-peel and Fe₃O₄-pulp samples, respectively. The synthesized magnetic nanoparticles show excellent colloidal stability in the aqueous solutions. The maximum hyperthermia temperatures are 42.28 °C and 42.48 °C for Fe₃O₄-peel and Fe₃O₄-pulp samples, respectively. Studies of the catalytic activity of magnetite were performed in decomposition of hydrogen peroxide in a batch mode. The degrees of H₂O₂ decomposition are 67.5% and 65.25% for the Fe₃O₄-peel and Fe₃O₄-pulp samples respectively. The high catalytic activity of the synthesized samples makes them promising candidates for the decomposition of hydrogen peroxide in wastewater disinfection.

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